PhD Studentship
Aerogel composites of porous crystalline materials for gas separation
Project Description:
The project will involve the design and construction of a suitable device for supercritical CO2 drying. Various techniques will be explored to embed porous crystallites within gel matrices before supercritical drying. The composites will then be subjected to mechanical testing, permeability studies, and gas sorption analyses to assess their performance against that of the pure porous crystallites.
Project Background:
In a recent perspective article, Scholl and Lively listed the “seven chemical separations to change the world” [1]. These include, inter alia, hydrocarbons from crude oil, alkenes from alkanes, greenhouse gases from dilute emissions, benzene derivatives from each other, and trace contaminants from water. Exploratory studies of porous materials for these types of separations are usually carried out with powdered crystallites. However, even if highly promising properties are discovered for a given material, it is unlikely that the material would be implemented commercially or industrially in its powdered form. For practical applications it is preferable to support the active material using a suitable matrix as a scaffold.
Aerogels are fascinating ultralight macroporous materials prepared by drying hydrogels using supercritical carbon dioxide. In a typical synthesis, a silica hydrogel is formed and then the water is exchanged for either methanol or ethanol. The solvent plays a supporting role in ensuring the structural integrity of the swollen material. When the solvent is removed by heating or evacuating, the gel usually collapses due to capillary action caused by surface tension. This collapse can be prevented by means of supercritical CO2 drying, where the solvent is replaced by CO2 under supercritical conditions (> 31.1 °C and 73.9 bar). The supercritical fluid has virtually no surface tension and is thus able to ‘wash’ out the solvent without causing the gel matrix to collapse. This leaves behind a nearly transparent ultralightweight and highly porous material. Although aerogels are themselves not suitable for selective gas separations, they may serve as highly suitable support materials for porous crystallites.
[1] D. S. Scholl and R. P. Lively, Nature 2016, 532, 435.
Funding:
This is a fully funded studentship for 3.5 years, applicable to Home applicants only. It covers all fees and provides an annual stipend of £19,237 paid in monthly instalments. Opportunities for collaboration and/or conference attendance are also available.
How to Apply
To make an application please email cohsstudentships@lincoln.ac.uk, providing a copy of your CV and a supporting statement outlining how your expertise and interests are relevant to the project.
The deadline for applications is 30 May 2025. Please note however that we will be considering applications as they are received and reserve the right to close for applications earlier.
For enquiries about the project please contact Professor Len Barbour (lbarbour@lincoln.ac.uk) and Dr Gareth Lloyd (glloyd@lincoln.ac.uk)
PhD Studentship
Flexible porous crystalline materials for gas separation
Project Description:
This project will involve the investigation of structure-property relationships of different classes of flexible porous materials. Unique structural and physico-chemical tools such as in situ X-ray crystallographic analysis of gas-loaded materials and pressure-ramped differential scanning calorimetry (P-DSC) will be used to elucidate the factors that influence gate-opening behaviour. The latter technique will be applied to measure heats of sorption/desorption directly, and to determine the kinetics of sorption. Furthermore, state-of-the-art instrumentation for gas sorption analysis and in situ powder X-ray diffraction analysis will be utilised, and a laboratory-scale pressure-swing adsorption system will be developed to screen materials for potential industrial applications
Project Background:
Scholl and Lively highlighted “seven chemical separations to change the world” in a high-profile perspective article [1]. In this context, this project is relevant to the following separation processes: (i) hydrocarbons from crude oil, (ii) alkenes from alkanes, (iii) greenhouse gases from dilute emissions, (iv) benzene derivatives from each other, and (v) trace contaminants from water.
Porous materials offer vast potential as selective substrates for molecular recognition based on size exclusion and favourable intermolecular interactions. Over the past three decades, new classes of porous materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and porous molecular crystals (PMCs) have emerged as promising candidates for molecular sieving. In particular, structurally flexible crystalline materials generally offer higher working capacities for molecular inclusion/extraction owing to their hysteretic gate-opening and closing behaviour.
[1] D. S. Scholl and R. P. Lively, Nature 2016, 532, 435.
Funding:
This is a fully funded studentship for 3.5 years, applicable to Home applicants only. It covers all fees and provides an annual stipend of £19,237 paid in monthly instalments. Opportunities for collaboration and/or conference attendance are also available.
How to Apply:
To make an application please email cohsstudentships@lincoln.ac.uk, providing a copy of your CV and a supporting statement outlining how your expertise and interests are relevant to the project.
The deadline for applications is 30 May 2025. Please note however that we will be considering applications as they are received and reserve the right to close for applications earlier.
For enquiries about the project please contact Professor Len Barbour (lbarbour@lincoln.ac.uk) and Dr Gareth Lloyd (glloyd@lincoln.ac.uk)
PhD Studentship
Phylogenetic resolution and a new evolutionary timescale for Temnospondyli (Tetrapoda: Amphibia)
Project Description:
Applications are invited for a full-time PhD position at the University of Lincoln's School of Natural Sciences to work with Dr Marcello Ruta (Principal Investigator) on phylogenetic, macroevolutionary, and macroecological aspects of the origin and diversification of tetrapods (the limbed vertebrates) with a main focus on temnospondyl amphibians, the largest radiation of early tetrapods. This post is funded by a Leverhulme Trust Research Project Grant to Dr Marcello Ruta, entitled “Key Innovations as Evolutionary Drivers of the Fish-Tetrapod Transition”, and is in partnership with the Universities of Bath (Co-Investigator Professor Matthew Wills) and Uppsala (Co-Investigator Professor Per Ahlberg)
Supervisory Team:
Dr Marcello Ruta, University of Lincoln, UK; Professor Matthew Wills, University of Bath, UK; Professor Per Ahlberg, University of Uppsala, Sweden.
Project Background:
Context - Temnospondyli are the most speciose, geologically most widespread, and ecologically most diverse group of early tetrapods (limbed vertebrates), with a fossil record ranging from Lower Carboniferous, ~336 million years ago, to uppermost Lower Cretaceous, ~100 Ma. Over 350 species are known, and several new discoveries occur at a steady pace. Temnospondyls are distinguished from other early tetrapods by a set of unique skeletal features, notably a pair of large openings on the palate separated by an elongate, strut-like anterior process of the braincase. In addition, this group is of remarkable zoological interest as it is implicated in the enduring debate on the ancestry of amphibians. Given their sheer diversity and abundance, temnospondyls provide a rich source of data for investigating life-history traits, ontogenetic changes, and functional specializations. Crucially, however, tempo and mode of morphological evolution and lineage diversification within the group lag. To address these themes, an all-encompassing and robust phylogeny is needed.
Rationale – Most major groups of temnospondyls are sufficiently well diagnosed, but their interrelationships are in a state of flux. Published phylogenies reveal substantial conflict involving the placement of some problematic species, the sequence of branching events within certain groups, and the mutual relationships between major lineages. Factors responsible for this conflict include character and species selection across different studies, discrepancies in character description, formulation, and coding, and methodologies for reconstructing phylogenies. The impact of different character/species samples and character coding on phylogenetic resolution is especially vexing and requires in-depth scrutiny. Only a handful of temnospondyl datasets have been subjected to extensive revision. Therefore, additional effort in this area is critical.
Main Objectives – The project has three integrated objectives: (1) resolution of outstanding areas of uncertainty in temnospondyl phylogeny; (2) production of a new phylogeny-based timescale for temnospondyl diversification; (3) quantification of morphological evolution, with emphasis on skull shape and dimensions, and driven trends.
Research Questions – (1) Did temnospondyls experience an early burst of morphological diversification? (2) Did evolutionary changes show directionality? (3) Was speciation linked to the origin of specific traits?
Methods – Published phylogenetic datasets will be augmented through character and species inclusion and checked for consistency in character formulation and coding. First-hand specimen observations will assist in gleaning additional information for a representative sample of temnospondyls from all major groups. The resulting comprehensive dataset will be subjected to phylogenetic analyses using different methods. Phylogenies will be time-calibrated using fossil ages and a variety of sampling, origination, and extinction rates. Such phylogenies will subsequently be employed to evaluate the direction, magnitude, and distribution (temporal and groupwise) of evolutionary rates, and to establish how morphological diversity of species was partitioned through time, by groups, and in the aftermath of major faunal turnovers, including two extinction events. Alongside analyses of disparity using differences in phylogenetic trait coding, the project will explore complex morphological features of the skull using coordinates of geometric points digitised on cranial structures of interest.
Project Roles:
The successful candidate will primarily undertake research on temnospondyl amphibians, the most diverse group of early tetrapods. They will work closely with all personnel on the grant to assist with data collections. The successful candidate will be first author on all publications stemming from their dissertation, but will also co-author additional papers with the PA, RA, and co-applicants, in particular publications that tackle similar research themes, such as group expansion and decline, shape disparity, and evolutionary trends. Publications will primarily include peer-reviewed research papers, based upon individual thesis chapters. There will also be scope for producing descriptive monographs of selected temnospondyls species.
Applicant Profile:
We are seeking a driven individual working primarily under the remits of the project's chief objectives. Trained by all team members, they will primarily undertake independent research, but also assist with data collection, curation, and databasing, processing and interpretation of phylogenetic and morphological datasets, assisting with preparation of manuscripts and conference presentations, and contributing to outreach and impact activities. The applicant will have prime opportunities to interact with international specialists in the research areas covered by the proposal, acquire transferable and discipline-specific skills, and engage in networking activities, facilitating career progression.
This project will ideally suit candidates with at least a BSc (2:1) honours degree in Zoology or Palaeontology. The successful applicant will also demonstrate a good knowledge of vertebrate morphology and evolution and at least basic analytical and statistical skills
Training:
We have a strong track record of providing first-class training in our institutions, attracting able and motivated individuals and producing talented undergraduates and postgraduates. Under the project supervisory team’s guidance, the student can receive solid training in macroevolutionary analysis and deliver work of publishable standards in high-profile, peer-reviewed journals. They can acquire discipline-specific skills, including, but not limited to: shape analysis, from data collection and processing to interpretation of results; comparative phylogenetic methods, designed to quantify tempo and mode of morphological evolution; advanced statistical methods in quantitative macroevolutionary analysis, such as trait correlations, rates and shift of change, and evolutionary trends. In addition, they can master transferable skills, such as: time management and planning; experimental design, from conception to delivery; poster presentation; academic writing; verbal communication; and critical evaluation of results. The student will be supported through in-person and online meetings (at least once a week), through provision of scripts with accompanying explanatory notes for running analyses and tests, guidance through the most recent literature on the subject covered by the studentship, and recording (e.g., via TEAMS) of software use demonstrations.
Funding:
This studentship is fully funded for 3 years (start date: 1 July 2025), covers all fees, and provides an annual stipend paid in monthly instalments. For 2024/25, this is £19,237 with slight increases each year at the rate set by UKRI.
There are several opportunities for both national and international collaborations, as well as attendance at scientific conferences.
Eligibility:
Due to funder restrictions, we can only accept applications from home applicants.
Applicant Profile:
We are seeking a driven individual working primarily under the remits of the project's chief objectives. Trained by all team members, they will primarily undertake independent research, but also assist with data collection, curation, and databasing, processing and interpretation of phylogenetic and morphological datasets, assisting with preparation of manuscripts and conference presentations, and contributing to outreach and impact activities. The applicant will have prime opportunities to interact with international specialists in the research areas covered by the proposal, acquire transferable and discipline-specific skills, and engage in networking activities, facilitating career progression.
This project will ideally suit candidates with at least a BSc (2:1) honours degree in Zoology or Palaeontology. The successful applicant will also demonstrate a good knowledge of vertebrate morphology and evolution and at least basic analytical and statistical skills
How to Apply
To apply for this position, please email cohsstudentships@lincoln.ac.uk, providing the following documents: a copy of your updated CV; a cover letter (max 2000 words) that includes a supporting statement explaining your interest in the advertised position, the relevance of your expertise to the project, and your vision for the development of the project’s research areas; and two recent reference letters.
Deadline for Application:
The deadline for applications is Monday, 19 May 2025. Applications will be considered as they are received. We anticipate completion of the shortlisting on Wednesday, 21 May 2025. Interviews are currently scheduled to take place on Friday, 30 May 2025.
For enquiries about the project please contact Dr Marcello Ruta (mruta@lincoln.ac.uk).